Dynamics of solid alanine by means of nuclear magnetic resonance relaxometry
PBN-AR
Instytucja
Wydział Matematyki i Informatyki (Uniwersytet Warmińsko-Mazurski w Olsztynie)
Informacje podstawowe
Główny język publikacji
angielski
Czasopismo
JOURNAL OF CHEMICAL PHYSICS (35pkt w roku publikacji)
ISSN
0021-9606
EISSN
1089-7690
Wydawca
AMER INST PHYSICS
DOI
URL
Rok publikacji
2017
Numer zeszytu
16
Strony od-do
164501
Numer tomu
146
Link do pełnego tekstu
Identyfikator DOI
Liczba arkuszy
0,5
Autorzy
Pozostali autorzy
+ 2
Streszczenia
Język
angielski
Treść
1H nuclear magnetic resonance relaxometry was applied to investigate the dynamics of l-alanine in the solid phase (powder). The experimental studies were carried out in a very broad frequency range, covering four orders of magnitude-from 4 kHz to 40 MHz (referring to the 1H resonance frequency) in order to probe motional processes of much different time scales by a single experiment. To get access to the dynamics of different proton groups of alanine, the 1H spin-lattice relaxation measurements were performed for non-deuterated and partially deuterated alanine. The experiments were carried out in the temperature range of 293 K-370 K (non-deuterated alanine) and 318 K-370 K (partially deuterated alanine). As a result of a thorough theoretical analysis of the extensive set of experimental results, three motional processes occurring on different time scales are identified and quantitatively described. The slowest process occurs on a time scale of μs and it is attributed to the collective dynamics of a 3D hydrogen bond network of alanine, while the intermediate, attributed to the dynamics of the NH3 group, corresponds to the range of tenths of ns. The fast process describes the rotation of the CH3 group.
Inne
System-identifier
PX-599c0703d5dee4caa6b768f4
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