Antiferromagnetic spin glass-like behavior in sintered multiferroic Aurivillius Bim+1Ti3Fem−3O3m+3 compounds
PBN-AR
Instytucja
Wydział Elektrotechniki i Informatyki (Politechnika Lubelska)
Informacje podstawowe
Główny język publikacji
angielski
Czasopismo
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
ISSN
0304-8853
EISSN
Wydawca
DOI
URL
Rok publikacji
2013
Numer zeszytu
Strony od-do
27-34
Numer tomu
342
Identyfikator DOI
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Autorzy
Pozostali autorzy
+ 6
Streszczenia
Język
EN
Treść
The structure, hyperfine interactions and magnetic properties of the series of multiferroic Bim+1Ti3Fem−3O3m+3 Aurivillius compounds with m=4–8 were studied using X-ray diffraction, 57Fe Mössbauer spectroscopy and vibrating sample magnetometry. Samples were prepared by the conventional solid-state sintering method. Bulk magnetic measurements showed that for m=4 the compound is paramagnetic down to 2 K while in the compound with m=5 the antiferromagnetic type transition was observed at 11 K. In the case of compounds with m=6–8 much more complex magnetic behavior was found. For these compounds a gradual spin freezing and antiferromagnetic spin glass-like ordering were observed on decreasing temperature. The temperature of spin glass freezing was determined as 260, 280 and 350 K for m=6, 7 and 8, respectively. Room-temperature Mössbauer spectra of all the compounds studied confirm their paramagnetic state. However, liquid nitrogen and liquid helium temperature measurements reveal magnetic ordering with a residual paramagnetic phase contribution for the compounds with m=5–8.
Inne
System-identifier
5307
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