$CO_{2}$ adsorption properties of char produced from brown coal impregnated with alcohol amine solutions
PBN-AR
Instytucja
Wydział Energetyki i Paliw (Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie)
##### Informacje podstawowe
Główny język publikacji
EN
Czasopismo
Environmental Monitoring and Assessment
ISSN
0167-6369
EISSN
1573-2959
Wydawca
Springer
Rok publikacji
2016
Numer zeszytu
7
Strony od-do
1--11
Numer tomu
188
Identyfikator DOI
Liczba arkuszy
0.78
##### Autorzy
(liczba autorów: 3)
EN
brown coal
amines
impregnation
##### Streszczenia
Język
EN
Treść
Carbon dioxide (CO2) emission reduction is critical to mitigating climate change. Power plants for heating and industry are significant sources of CO2 emissions. There is a need for identifying and developing new, efficient methods to reduce CO2 emissions. One of the methods used is flue gas purification by CO2 capture through adsorption. This study aimed to develop CO2 adsorbent out of modified brown coal impregnated with solutions of first-, second-, and third-order amines. Low-temperature nitrogen adsorption isotherms and CO2 isotherms were measured for the prepared samples. The results of experiments unexpectedly revealed that CO2 sorption capacity decreased after impregnation. Due to lack of strait trends in CO2 sorption capacity decrease, the results were closely analyzed to find the reason for the inconsistencies. It was revealed that different amines represent different affinities for CO2 and that the size and structure of impregnating factor has influence on the CO2 sorption capacity of impregnated material. The character of a support was also noticeable as well for impregnation results as for the affinity to CO2. The influence of amine concentration used was investigated along with the comparison on how the theoretical percentage of the impregnation on the support influenced the results. The reaction mechanism of tertiary amine was taken into consideration in connection to no presence of water vapor during the experiments. Key findings were described in the work and provide a strong basis for further studies on CO2 adsorption on amine-impregnated support.
original article
peer-reviewed
##### Inne
System-identifier
idp:098801
Crossref
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