Characterization of poly(amic acid)s and resulting polyimides bearing azobenzene moieties including investigations of thermal imidization kinetics and photoinduced anisotropy
PBN-AR
Instytucja
Wydział Matematyki, Fizyki i Chemii (Uniwersytet Śląski w Katowicach)
Informacje podstawowe
Główny język publikacji
EN
Czasopismo
POLYMER INTERNATIONAL
ISSN
0959-8103
EISSN
Wydawca
URL
Rok publikacji
2015
Numer zeszytu
1
Strony od-do
76-87
Numer tomu
64
Identyfikator DOI
Liczba arkuszy
0,6
Autorzy
Pozostali autorzy
+ 5
Słowa kluczowe
EN
azopolymers
imidization
poly(amic acid)s
polyimides
surface relief gratings
Streszczenia
Język
EN
Treść
Azobenzene-containing poly(amic acid)s and resulting polyimides were synthesized. Polymers differedin the polymer backbone structure and the position at which the azobenzene group was attached to the polymer chain. Polymers were characterized and evaluated using Fourier transform infrared, 1H NMR and UV-visible spectroscopies, X-ray diffraction, differential scanning calorimetry (DSC) and thermogravimetric analysis. Polyimides revealed glass transition temperatures in the range 160–265 ∘C, and thermal stability with decomposition temperatures in the range 336–444 ∘C. The thermal imidization kinetics of poly(amic acid)s was investigated by means of DSC. Kinetic parameters, such as the activation energy (E) and the frequency factor, were estimated using the Ozawa and Kissinger models. The values of E, determined using both methods, were in the range 142.52–200.92 kJ mol−1. The photoinduced optical anisotropy (POA) was studied in the obtained azopolymers using a holographic grating recording technique. Surface relief gratings, which appeared after light exposure, were observed using atomic force microscopy. For the first time to the best of our knowledge, photoinduced anisotropy in poly(amic acid)s was studied and compared with POA in their polyimide analogues.
Inne
System-identifier
0192600106810
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