Highly ordered structural organization of organic semiconductor monolayers on HOPG and Au(111) - STM studies of alkylphenyl N-substituted perylene diimide at liquid–solid interface
PBN-AR
Instytucja
Wydział Chemiczny (Politechnika Warszawska)
Informacje podstawowe
Główny język publikacji
en
Czasopismo
Surface Science
ISSN
0039-6028
EISSN
Wydawca
Elsevier BV - North-Holland
DOI
URL
Rok publikacji
2013
Numer zeszytu
Strony od-do
61-67
Numer tomu
607
Identyfikator DOI
Liczba arkuszy
0.5
Autorzy
Pozostali autorzy
+ 3
Słowa kluczowe
en
perylene diimide, scanning tunneling microscopy, self-organization, organic electronics, organic semiconductors
Streszczenia
Język
en
Treść
Scanning tunneling microscopy was used to investigate self-organization in mono- or multilayers of an organic semiconductor used for the fabrication of n-channel field effect transistors, namely N,N′-bis(4-n-butylphenyl)-perylene-3,4:9,10-tetracarboxylic-diimide (4-n-BuPh-PTCDI). Two types of substrates were used: HOPG and reconstructed Au(111). All investigations were performed at liquid–solid interface in a trichlorobenzene solution. Monolayers deposited directly on the HOPG show a brick-wall organization with individual molecules lying flat on the substrate surface (the planes of aromatic cores being parallel to this surface). Monolayers obtained by controlled dissolution of a previously deposited multilayer show a different 2D organization in which individual molecules are in the edge-on position i.e. stand perpendicular to the substrate surface with their long axis parallel to it. This finding clearly demonstrates the effect of the upper-lying layers on the first monolayer which changes the balance in the molecule–substrate and molecule–molecule interactions, leading to a rotation of the molecules in the first layer. A very similar structure of densely packed molecules, oriented perpendicular to the substrate, is also found for the monolayer deposited on the Au(111) surface. © 2012 Elsevier B.V. All rights reserved
Inne
System-identifier
WUT395621
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