Effect of the ruthenium loading and barium addition on the activity of ruthenium/carbon catalysts in carbon monoxide methanation
PBN-AR
Instytucja
Wydział Chemiczny (Politechnika Warszawska)
Informacje podstawowe
Główny język publikacji
en
Czasopismo
Polish Journal of Chemical Technology
ISSN
1509-8117
EISSN
Wydawca
Wydawnictwo Uczelniane Zachodniopomorskiego Uniwersytetu Technologicznego w Szczecinie
DOI
Rok publikacji
2014
Numer zeszytu
4
Strony od-do
106-110
Numer tomu
16
Identyfikator DOI
Liczba arkuszy
0.5
Słowa kluczowe
en
CO methanation, ruthenium catalyst, barium, carbon support
Streszczenia
Język
en
Treść
A group of supported ruthenium catalysts was prepared and tested in methanation of small CO amounts (7000 ppm) in hydrogen-rich streams. High surface area graphitized carbon (484 m2/g) was used as a support for ruthenium and RuCl3 was used as a Ru precursor. Some of the Ru/C systems were additionally doped with barium (Ba(NO3)2 was barium precursor). The catalysts were characterized by the chemisorption technique using CO as an adsorbate. To determine the resistance of the catalysts to undesired carbon support methanation, the TG-MS experiments were performed. They revealed that the barium addition inhibits support losses. The studies of CO methanation (fl ow reactor, atmospheric pressure) have shown that some of the supported ruthenium catalysts exhibit high activities referred to the metal mass. The catalytic properties of ruthenium proved to be dependent on metal dispersion. Some of the Ru/C and Ba-Ru/C systems exhibit higher activity in CO hydrogenation than the commercial nickel-based catalyst.
Inne
System-identifier
WUT1b19bd8795c24c8f97a16da51d07dada
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